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Heterotrimetallic Carbon Dioxide Copolymerization and Switchable Catalysts: Sodium is the Key to High Activity and Unusual Selectivity
A challenge in polymer synthesis using CO(2) is to precisely control CO(2) placement in the backbone and chain end groups. Here, a new catalyst class delivers unusual selectivity and is self‐switched between different polymerization cycles to construct specific sequences and desirable chain‐end chem...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251569/ https://www.ncbi.nlm.nih.gov/pubmed/33971064 http://dx.doi.org/10.1002/anie.202101180 |