Cargando…
Heterotrimetallic Carbon Dioxide Copolymerization and Switchable Catalysts: Sodium is the Key to High Activity and Unusual Selectivity
A challenge in polymer synthesis using CO(2) is to precisely control CO(2) placement in the backbone and chain end groups. Here, a new catalyst class delivers unusual selectivity and is self‐switched between different polymerization cycles to construct specific sequences and desirable chain‐end chem...
Autores principales: | Plajer, Alex J., Williams, Charlotte K. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251569/ https://www.ncbi.nlm.nih.gov/pubmed/33971064 http://dx.doi.org/10.1002/anie.202101180 |
Ejemplares similares
-
Heterocycle/Heteroallene Ring‐Opening Copolymerization: Selective Catalysis Delivering Alternating Copolymers
por: Plajer, Alex J., et al.
Publicado: (2021) -
Synergic Heterodinuclear
Catalysts for the Ring-Opening
Copolymerization (ROCOP) of Epoxides, Carbon Dioxide, and Anhydrides
por: Diment, Wilfred T., et al.
Publicado: (2022) -
Ti(IV)–Tris(phenolate) Catalyst Systems for the Ring-Opening Copolymerization
of Cyclohexene Oxide and Carbon Dioxide
por: Raman, Sumesh K., et al.
Publicado: (2020) -
Heterodinuclear Zn(II), Mg(II) or Co(III) with Na(I) Catalysts for Carbon Dioxide and Cyclohexene Oxide Ring Opening Copolymerizations
por: Lindeboom, Wouter, et al.
Publicado: (2021) -
Insights into the Mechanism
of Carbon Dioxide and
Propylene Oxide Ring-Opening Copolymerization Using a Co(III)/K(I)
Heterodinuclear Catalyst
por: Deacy, Arron C., et al.
Publicado: (2022)