Merging Pincer Motifs and Potential Metal–Metal Cooperativity in Cobalt Dinitrogen Chemistry: Efficient Catalytic Silylation of N(2) to N(SiMe(3))(3)

Using a pyrazolate‐bridged dinucleating ligand that provides two proximate pincer‐type PNN binding sites (“two‐in‐one pincer”), different synthetic routes have been developed towards its dicobalt(I) complex 2 that features a twice deprotonated ligand backbone and two weakly activated terminal N(2) s...

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Detalles Bibliográficos
Autores principales: Li, Ming, Gupta, Sandeep K., Dechert, Sebastian, Demeshko, Serhiy, Meyer, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251579/
https://www.ncbi.nlm.nih.gov/pubmed/33829680
http://dx.doi.org/10.1002/anie.202101387

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251579/
https://www.ncbi.nlm.nih.gov/pubmed/33829680
http://dx.doi.org/10.1002/anie.202101387

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