Cargando…
Merging Pincer Motifs and Potential Metal–Metal Cooperativity in Cobalt Dinitrogen Chemistry: Efficient Catalytic Silylation of N(2) to N(SiMe(3))(3)
Using a pyrazolate‐bridged dinucleating ligand that provides two proximate pincer‐type PNN binding sites (“two‐in‐one pincer”), different synthetic routes have been developed towards its dicobalt(I) complex 2 that features a twice deprotonated ligand backbone and two weakly activated terminal N(2) s...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251579/ https://www.ncbi.nlm.nih.gov/pubmed/33829680 http://dx.doi.org/10.1002/anie.202101387 |