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Strong Lewis and Brønsted Acidic Sites in the Borosulfate Mg(3)[H(2)O→B(SO(4))(3)](2)

Borosulfates provide fascinating structures and properties that go beyond a pure analogy to silicates. Mg(3)[H(2)O→B(SO(4))(3)](2) is the first borosulfate featuring a boron atom solely coordinated by three tetrahedra. Thus, the free Lewis acidic site forms a Lewis acid–base adduct with a water mole...

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Detalles Bibliográficos
Autores principales: Netzsch, Philip, Stroh, Regina, Pielnhofer, Florian, Krossing, Ingo, Höppe, Henning A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251581/
https://www.ncbi.nlm.nih.gov/pubmed/33751735
http://dx.doi.org/10.1002/anie.202016920