Binding of a TlCl Entity by a Tetragold Tetramercaptothiacalixarene Metalloligand via Metallophilic Interactions

The successive auration of p‐tert‐butyltetramercaptotetrathiacalix[4]arene, H(4)(MTC[4]), with gold(I) phosphine units was investigated. Through deprotonation with NaOMe, followed by salt metathesis reactions with (PR(3))AuCl (R=Me, Ph) complexes with two and three [(PR(3))Au](+) moieties could be p...

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Detalles Bibliográficos
Autores principales: Frank, N., Pryjomska‐Ray, I., Grubert, L., Hecht, S., Usvyat, D., Limberg, C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251583/
https://www.ncbi.nlm.nih.gov/pubmed/33780048
http://dx.doi.org/10.1002/chem.202100298

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251583/
https://www.ncbi.nlm.nih.gov/pubmed/33780048
http://dx.doi.org/10.1002/chem.202100298

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