Cobalt Diazo‐Compounds: From Nitrilimide to Isocyanoamide via a Diazomethanediide Fleeting Intermediate

Lithium trimethylsilyldiazomethanide and a cobalt (II) precursor with an N‐anchored tris‐NHC (TIMEN(mes)) ligand provide access to the cobalt nitrilimide 1. Complex 1 was structurally characterized by single‐crystal X‐ray diffractometry (SC‐XRD) and its electronic structure was examined in detail, i...

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Detalles Bibliográficos
Autores principales: Aghazada, Sadig, Fehn, Dominik, Heinemann, Frank W., Munz, Dominik, Meyer, Karsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251593/
https://www.ncbi.nlm.nih.gov/pubmed/33559940
http://dx.doi.org/10.1002/anie.202016539

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251593/
https://www.ncbi.nlm.nih.gov/pubmed/33559940
http://dx.doi.org/10.1002/anie.202016539

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