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Cobalt Diazo‐Compounds: From Nitrilimide to Isocyanoamide via a Diazomethanediide Fleeting Intermediate
Lithium trimethylsilyldiazomethanide and a cobalt (II) precursor with an N‐anchored tris‐NHC (TIMEN(mes)) ligand provide access to the cobalt nitrilimide 1. Complex 1 was structurally characterized by single‐crystal X‐ray diffractometry (SC‐XRD) and its electronic structure was examined in detail, i...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251593/ https://www.ncbi.nlm.nih.gov/pubmed/33559940 http://dx.doi.org/10.1002/anie.202016539 |