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Light‐Driven gem Hydrogenation: An Orthogonal Entry into “Second‐Generation” Ruthenium Carbene Catalysts for Olefin Metathesis

The newly discovered light‐driven gem hydrogenation of alkynes opens an unconventional yet efficient entry into five‐coordinate Grubbs‐type ruthenium carbene complexes with cis‐disposed chloride ligands. Representatives of this class featuring a chelate substructure formed by an iodo‐substituted ben...

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Detalles Bibliográficos
Autores principales: Zachmann, Raphael J., Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251631/
https://www.ncbi.nlm.nih.gov/pubmed/33871083
http://dx.doi.org/10.1002/chem.202101176