Iron‐Catalyzed Wacker‐type Oxidation of Olefins at Room Temperature with 1,3‐Diketones or Neocuproine as Ligands

Herein, we describe a convenient and general method for the oxidation of olefins to ketones using either tris(dibenzoylmethanato)iron(III) [Fe(dbm)(3)] or a combination of iron(II) chloride and neocuproine (2,9‐dimethyl‐1,10‐phenanthroline) as catalysts and phenylsilane (PhSiH(3)) as additive. All r...

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Detalles Bibliográficos
Autores principales: Puls, Florian, Linke, Philipp, Kataeva, Olga, Knölker, Hans‐Joachim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251641/
https://www.ncbi.nlm.nih.gov/pubmed/33856090
http://dx.doi.org/10.1002/anie.202103222

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251641/
https://www.ncbi.nlm.nih.gov/pubmed/33856090
http://dx.doi.org/10.1002/anie.202103222

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