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Iron‐Catalyzed Wacker‐type Oxidation of Olefins at Room Temperature with 1,3‐Diketones or Neocuproine as Ligands
Herein, we describe a convenient and general method for the oxidation of olefins to ketones using either tris(dibenzoylmethanato)iron(III) [Fe(dbm)(3)] or a combination of iron(II) chloride and neocuproine (2,9‐dimethyl‐1,10‐phenanthroline) as catalysts and phenylsilane (PhSiH(3)) as additive. All r...
Autores principales: | Puls, Florian, Linke, Philipp, Kataeva, Olga, Knölker, Hans‐Joachim |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251641/ https://www.ncbi.nlm.nih.gov/pubmed/33856090 http://dx.doi.org/10.1002/anie.202103222 |
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