Enantio‐ and Regioconvergent Nickel‐Catalyzed C(sp(3))−C(sp(3)) Cross‐Coupling of Allylic Electrophiles Steered by a Silyl Group

A two‐step sequence for the enantio‐ and diastereoselective synthesis of exclusively alkyl‐substituted acyclic allylic systems with a stereocenter in the allylic position is reported. The asymmetric induction and the site selectivity are controlled in an enantio‐ and regioconvergent nickel‐catalyzed...

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Detalles Bibliográficos
Autores principales: Kranidiotis‐Hisatomi, Nektarios, Yi, Hong, Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251714/
https://www.ncbi.nlm.nih.gov/pubmed/33822445
http://dx.doi.org/10.1002/anie.202102233

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251714/
https://www.ncbi.nlm.nih.gov/pubmed/33822445
http://dx.doi.org/10.1002/anie.202102233

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