Cargando…

Enantio‐ and Regioconvergent Nickel‐Catalyzed C(sp(3))−C(sp(3)) Cross‐Coupling of Allylic Electrophiles Steered by a Silyl Group

A two‐step sequence for the enantio‐ and diastereoselective synthesis of exclusively alkyl‐substituted acyclic allylic systems with a stereocenter in the allylic position is reported. The asymmetric induction and the site selectivity are controlled in an enantio‐ and regioconvergent nickel‐catalyzed...

Descripción completa

Detalles Bibliográficos
Autores principales:	Kranidiotis‐Hisatomi, Nektarios, Yi, Hong, Oestreich, Martin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251714/ https://www.ncbi.nlm.nih.gov/pubmed/33822445 http://dx.doi.org/10.1002/anie.202102233

Ejemplares similares

Nickel‐Catalyzed, Reductive C(sp(3))−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes
por: Zhang, Liangliang, et al.
Publicado: (2021)

Consecutive β,β′‐Selective C(sp(3))−H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C(6)F(5))(3)
por: Fang, Huaquan, et al.
Publicado: (2021)

Enantioselective C(sp(3))–C(sp(3)) cross-coupling of non-activated alkyl electrophiles via nickel hydride catalysis
por: Bera, Srikrishna, et al.
Publicado: (2021)

Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes
por: Zhang, Liangliang, et al.
Publicado: (2019)

Modulating stereoselectivity in allylic C(sp(3))-H bond arylations via nickel and photoredox catalysis
por: Huang, Long, et al.
Publicado: (2023)

Theoretical investigation on the effect of the ligand on bis-silylation of C(sp)–C(sp) by Ni complexes
por: Hui, Li, et al.
Publicado: (2022)

Enantio‐ and Diastereoselective Copper‐Catalyzed Allylboration of Alkynes with Allylic gem‐Dichlorides
por: Chaves‐Pouso, Andrea, et al.
Publicado: (2022)

Electrochemical Nickel-Catalyzed C(sp(3))–C(sp(3)) Cross-Coupling of Alkyl Halides with Alkyl Tosylates
por: Ibrahim, Malek Y. S., et al.
Publicado: (2023)

Palladium-catalyzed regio- and enantioselective migratory allylic C(sp(3))-H functionalization
por: Chen, Ye-Wei, et al.
Publicado: (2021)

Nickel-catalyzed regio- and enantio-selective Markovnikov hydromonofluoroalkylation of 1,3-dienes
por: Liao, Ling, et al.
Publicado: (2022)

Metal‐Free Hydrosilylation of Ketenes with Silicon Electrophiles: Access to Fully Substituted Aldehyde‐Derived Silyl Enol Ethers
por: Roy, Avijit, et al.
Publicado: (2021)

Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones
por: Feng, Jian-Jun, et al.
Publicado: (2019)

Dual nickel and Lewis acid catalysis for cross-electrophile coupling: the allylation of aryl halides with allylic alcohols
por: Jia, Xue-Gong, et al.
Publicado: (2017)

Photoredox mediated nickel catalyzed C(sp(3))–H thiocarbonylation of ethers
por: Kang, Byungjoon, et al.
Publicado: (2017)

C(sp(3))−C(sp(3)) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine
por: Cao, Dawei, et al.
Publicado: (2021)

Cobalt-catalyzed nucleophilic addition of the allylic C(sp(3))–H bond of simple alkenes to ketones
por: Mita, Tsuyoshi, et al.
Publicado: (2018)

Pyridylic anions are soft nucleophiles in the palladium-catalyzed C(sp(3))–H allylation of 4-alkylpyridines
por: Wasfy, Nour, et al.
Publicado: (2020)

Site-selective amination and/or nitrilation via metal-free C(sp(2))–C(sp(3)) cleavage of benzylic and allylic alcohols
por: Anugu, Raghunath Reddy, et al.
Publicado: (2022)

Iridium-catalyzed enantioselective olefinic C(sp(2))–H allylic alkylation
por: Sarkar, Rahul, et al.
Publicado: (2021)

Intermolecular Carbosilylation of α‐Olefins with C(sp(3))−C(sp) Bond Formation Involving Silylium‐Ion Regeneration
por: He, Tao, et al.
Publicado: (2022)

Cleavage of non-polar C(sp(2))‒C(sp(2)) bonds in cycloparaphenylenes via electric field-catalyzed electrophilic aromatic substitution
por: Lin, Junfeng, et al.
Publicado: (2023)

Allylic C(sp(3))–H alkylation via synergistic organo- and photoredox catalyzed radical addition to imines
por: Jia, Jiaqi, et al.
Publicado: (2020)

Nickel-catalyzed cross-electrophile allylation of vinyl bromides and the modification of anti-tumour natural medicine β-elemene
por: Ye, Yang, et al.
Publicado: (2022)

Regioselective molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications
por: Salman, Muhammad, et al.
Publicado: (2020)

Versatile telluracycle synthesis via the sequential electrophilic telluration of C(sp(2))–Zn and C(sp(2))–H bonds
por: Wu, Bin, et al.
Publicado: (2017)

Correction: Iridium-catalyzed enantioselective olefinic C(sp(2))–H allylic alkylation
por: Sarkar, Rahul, et al.
Publicado: (2021)

Catalytic Stereospecific Allyl–Allyl Cross-Coupling of Internal Allyl Electrophiles with AllylB(pin)
por: Le, Hai, et al.
Publicado: (2014)

Reductive C(sp(3))–C(sp(3)) homo-coupling of benzyl or allyl halides with H(2) using a water-soluble electron storage catalyst
por: Yatabe, Takeshi, et al.
Publicado: (2021)

The direct arylation of allylic sp(3) C–H bonds via organocatalysis and photoredox catalysis
por: Cuthbertson, James D., et al.
Publicado: (2015)

Benzylic C(sp(3))–C(sp(2)) cross-coupling of indoles enabled by oxidative radical generation and nickel catalysis
por: Kim, Weonjeong, et al.
Publicado: (2021)

Electroreductive Nickel‐Catalyzed Thiolation: Efficient Cross‐Electrophile Coupling for C−S Formation
por: Ang, Nate W. J., et al.
Publicado: (2021)

Pd-catalyzed cross-electrophile Coupling/C–H alkylation reaction enabled by a mediator generated via C(sp(3))–H activation
por: Wu, Zhuo, et al.
Publicado: (2021)

Enantio- and Z-selective synthesis of functionalized alkenes bearing tertiary allylic stereogenic center
por: Ge, Luo, et al.
Publicado: (2023)

Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp(3))-H Bond Allylation
por: Zhang, Jing, et al.
Publicado: (2019)

Modular allylation of C(sp(3))–H bonds by combining decatungstate photocatalysis and HWE olefination in flow
por: Capaldo, Luca, et al.
Publicado: (2022)

Catalytic asymmetric defluorinative allylation of silyl enol ethers
por: Duran, Jordi, et al.
Publicado: (2023)

Catalytic asymmetric allylation of aldehydes with alkenes through allylic C(sp(3))–H functionalization mediated by organophotoredox and chiral chromium hybrid catalysis
por: Mitsunuma, Harunobu, et al.
Publicado: (2019)

Site-Selective C(sp(3))–C(sp)/C(sp(3))–C(sp(2)) Cross-Coupling Reactions Using Frustrated Lewis Pairs
por: Dasgupta, Ayan, et al.
Publicado: (2021)

Recent advances in Cu-catalyzed C(sp(3))–Si and C(sp(3))–B bond formation
por: Takale, Balaram S, et al.
Publicado: (2020)

The Merger of Benzophenone HAT Photocatalysis and Silyl Radical-Induced XAT Enables Both Nickel-Catalyzed Cross-Electrophile Coupling and 1,2-Dicarbofunctionalization of Olefins
por: Luridiana, Alberto, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_1i5iujrn2dja7ge6iikhd2ou8k