A Cavity‐Tailored Metal‐Organic Cage Entraps Gases Selectively in Solution and the Amorphous Solid State

Here we report the subcomponent self‐assembly of a truxene‐faced Zn(4)L(4) tetrahedron, which is capable of binding the smallest hydrocarbons in solution. By deliberately incorporating inward‐facing ethyl groups on the truxene faces, the resulting partially‐filled cage cavity was tailored to encapsu...

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Detalles Bibliográficos
Autores principales: Zhu, Jun‐Long, Zhang, Dawei, Ronson, Tanya K., Wang, Wenjing, Xu, Lin, Yang, Hai‐Bo, Nitschke, Jonathan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251750/
https://www.ncbi.nlm.nih.gov/pubmed/33768657
http://dx.doi.org/10.1002/anie.202102095

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251750/
https://www.ncbi.nlm.nih.gov/pubmed/33768657
http://dx.doi.org/10.1002/anie.202102095

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