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Hyperpolarization Effects in Parahydrogen Activation with Pnictogen Biradicaloids: Metal‐free PHIP and SABRE

Biradicaloids attract attention as a novel class of reagents that can activate small molecules such as H(2), ethylene and CO(2). Herein, we study activation of parahydrogen (nuclear spin‐0 isomer of H(2)) by a number of 4‐ and 5‐membered pnictogen biradicaloids based on hetero‐cyclobutanediyl [X(μ‐N...

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Detalles Bibliográficos
Autores principales: Zhivonitko, Vladimir V., Beer, Henrik, Zakharov, Danila O., Bresien, Jonas, Schulz, Axel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251785/
https://www.ncbi.nlm.nih.gov/pubmed/33725397
http://dx.doi.org/10.1002/cphc.202100141