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New Noncentrosymmetric Tetrel Pnictides Composed of Square‐Planar Gold(I) with Peculiar Bonding

Three novel isostructural equiatomic gold tetrel pnictides, AuSiAs, AuGeP, and AuGeAs, were synthesized and characterized. These phases crystallize in the noncentrosymmetric (NCS) monoclinic space group Cc (no. 9), featuring square‐planar Au within cis‐[AuTt(2)Pn(2)] units (Tt=tetrel, Si, Ge; Pn=pni...

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Detalles Bibliográficos
Autores principales: Lee, Shannon J., Won, Juyeon, Wang, Lin‐Lin, Jing, Dapeng, Harmer, Colin P., Mark, Justin, Akopov, Georgiy, Kovnir, Kirill
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251799/
https://www.ncbi.nlm.nih.gov/pubmed/33523500
http://dx.doi.org/10.1002/chem.202005312