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Synthesis and Multiple Subsequent Reactivity of Anionic cyclo‐E(3) Ligand Complexes (E=P, As)

A synthetic pathway for the synthesis of novel anionic sandwich complexes with a cyclo‐E(3) (E=P, As) ligand as an end deck was developed giving [Cp′′′Co(η(3)‐E(3))](−) (Cp′′′=1,2,4‐tri‐tert‐butylcyclopentadienyl, E=P ([5]), As ([6])) in good yields suitable for further reactivity studies. In the re...

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Detalles Bibliográficos
Autores principales: Piesch, Martin, Reichl, Stephan, Seidl, Michael, Balázs, Gábor, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251822/
https://www.ncbi.nlm.nih.gov/pubmed/33961722
http://dx.doi.org/10.1002/anie.202103683