Vapochromism and Magnetochemical Switching of a Nickel(II) Paddlewheel Complex by Reversible NH(3) Uptake and Release

Reaction of [NiCl(2)(PnH)(4)] (1) (PnH=6‐tert‐butyl‐pyridazine‐3‐thione) with NiCl(2) affords the binuclear paddlewheel (PW) complex [Ni(2)(Pn)(4)] (2). Diamagnetic complex 2 is the first example of a PW complex capable of reversibly binding and releasing NH(3). The NH(3) ligand in [Ni(2)(Pn)(4)(NH(...

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Detalles Bibliográficos
Autores principales: Fürpaß, Katharina M., Peschel, Lydia M., Schachner, Jörg A., Borisov, Sergey M., Krenn, Heinz, Belaj, Ferdinand, Mösch‐Zanetti, Nadia C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251872/
https://www.ncbi.nlm.nih.gov/pubmed/33773004
http://dx.doi.org/10.1002/anie.202102149

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251872/
https://www.ncbi.nlm.nih.gov/pubmed/33773004
http://dx.doi.org/10.1002/anie.202102149

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