Uranium versus Thorium: Synthesis and Reactivity of [η (5)‐1,2,4‐(Me(3)C)(3)C(5)H(2)](2)U[η (2)‐C(2)Ph(2)]

The synthesis, electronic structure, and reactivity of a uranium metallacyclopropene were comprehensively studied. Addition of diphenylacetylene (PhC≡CPh) to the uranium phosphinidene metallocene [η (5)‐1,2,4‐(Me(3)C)(3)C(5)H(2)](2)U=P‐2,4,6‐tBu(3)C(6)H(2) (1) yields the stable uranium metallacyclop...

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Detalles Bibliográficos
Autores principales: Wang, Deqiang, Ding, Wanjian, Hou, Guohua, Zi, Guofu, Walter, Marc D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251885/
https://www.ncbi.nlm.nih.gov/pubmed/33559922
http://dx.doi.org/10.1002/chem.202100089

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251885/
https://www.ncbi.nlm.nih.gov/pubmed/33559922
http://dx.doi.org/10.1002/chem.202100089

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