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Diversifying Metal–Ligand Cooperative Catalysis in Semi‐Synthetic [Mn]‐Hydrogenases

The reconstitution of [Mn]‐hydrogenases using a series of Mn(I) complexes is described. These complexes are designed to have an internal base or pro‐base that may participate in metal–ligand cooperative catalysis or have no internal base or pro‐base. Only Mn(I) complexes with an internal base or pro...

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Detalles Bibliográficos
Autores principales: Pan, Hui‐Jie, Huang, Gangfeng, Wodrich, Matthew D., Tirani, Farzaneh Fadaei, Ataka, Kenichi, Shima, Seigo, Hu, Xile
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251902/
https://www.ncbi.nlm.nih.gov/pubmed/33635597
http://dx.doi.org/10.1002/anie.202100443