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Diversifying Metal–Ligand Cooperative Catalysis in Semi‐Synthetic [Mn]‐Hydrogenases
The reconstitution of [Mn]‐hydrogenases using a series of Mn(I) complexes is described. These complexes are designed to have an internal base or pro‐base that may participate in metal–ligand cooperative catalysis or have no internal base or pro‐base. Only Mn(I) complexes with an internal base or pro...
Autores principales: | Pan, Hui‐Jie, Huang, Gangfeng, Wodrich, Matthew D., Tirani, Farzaneh Fadaei, Ataka, Kenichi, Shima, Seigo, Hu, Xile |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251902/ https://www.ncbi.nlm.nih.gov/pubmed/33635597 http://dx.doi.org/10.1002/anie.202100443 |
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