Surprising Homolytic Gas Phase Co−C Bond Dissociation Energies of Organometallic Aryl‐Cobinamides Reveal Notable Non‐Bonded Intramolecular Interactions

Aryl‐cobalamins are a new class of organometallic structural mimics of vitamin B(12) designed as potential ‘antivitamins B(12)’. Here, the first cationic aryl‐cobinamides are described, which were synthesized using the newly developed diaryl‐iodonium method. The aryl‐cobinamides were obtained as pai...

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Detalles Bibliográficos
Autores principales: Tsybizova, Alexandra, Brenig, Christopher, Kieninger, Christoph, Kräutler, Bernhard, Chen, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251903/
https://www.ncbi.nlm.nih.gov/pubmed/33560580
http://dx.doi.org/10.1002/chem.202004589

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251903/
https://www.ncbi.nlm.nih.gov/pubmed/33560580
http://dx.doi.org/10.1002/chem.202004589

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