Cargando…
Surprising Homolytic Gas Phase Co−C Bond Dissociation Energies of Organometallic Aryl‐Cobinamides Reveal Notable Non‐Bonded Intramolecular Interactions
Aryl‐cobalamins are a new class of organometallic structural mimics of vitamin B(12) designed as potential ‘antivitamins B(12)’. Here, the first cationic aryl‐cobinamides are described, which were synthesized using the newly developed diaryl‐iodonium method. The aryl‐cobinamides were obtained as pai...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251903/ https://www.ncbi.nlm.nih.gov/pubmed/33560580 http://dx.doi.org/10.1002/chem.202004589 |