Catalytic Oxygenation of Hydrocarbons by Mono‐μ‐oxo Dicopper(II) Species Resulting from O−O Cleavage of Tetranuclear Cu(I)/Cu(II) Peroxo Complexes

One of the challenges of catalysis is the transformation of inert C−H bonds to useful products. Copper‐containing monooxygenases play an important role in this regard. Here we show that low‐temperature oxygenation of dinuclear copper(I) complexes leads to unusual tetranuclear, mixed‐valent μ(4)‐pero...

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Detalles Bibliográficos
Autores principales: Jurgeleit, Ramona, Grimm‐Lebsanft, Benjamin, Flöser, Benedikt Maria, Teubner, Melissa, Buchenau, Sören, Senft, Laura, Hoffmann, Jonas, Naumova, Maria, Näther, Christian, Ivanović‐Burmazović, Ivana, Rübhausen, Michael, Tuczek, Felix
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251984/
https://www.ncbi.nlm.nih.gov/pubmed/33856088
http://dx.doi.org/10.1002/anie.202101035

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251984/
https://www.ncbi.nlm.nih.gov/pubmed/33856088
http://dx.doi.org/10.1002/anie.202101035

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