Cargando…

Catalytic Oxygenation of Hydrocarbons by Mono‐μ‐oxo Dicopper(II) Species Resulting from O−O Cleavage of Tetranuclear Cu(I)/Cu(II) Peroxo Complexes

One of the challenges of catalysis is the transformation of inert C−H bonds to useful products. Copper‐containing monooxygenases play an important role in this regard. Here we show that low‐temperature oxygenation of dinuclear copper(I) complexes leads to unusual tetranuclear, mixed‐valent μ(4)‐pero...

Descripción completa

Detalles Bibliográficos
Autores principales:	Jurgeleit, Ramona, Grimm‐Lebsanft, Benjamin, Flöser, Benedikt Maria, Teubner, Melissa, Buchenau, Sören, Senft, Laura, Hoffmann, Jonas, Naumova, Maria, Näther, Christian, Ivanović‐Burmazović, Ivana, Rübhausen, Michael, Tuczek, Felix
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251984/ https://www.ncbi.nlm.nih.gov/pubmed/33856088 http://dx.doi.org/10.1002/anie.202101035

Ejemplares similares

Exceptional Substrate Diversity in Oxygenation Reactions Catalyzed by a Bis(μ‐oxo) Copper Complex
por: Paul, Melanie, et al.
Publicado: (2020)

Tetrakis(μ-acetato-κ(2) O:O′)-bis[(3-pyridinecarboxaldehyde-κN′)]dicopper(II)(Cu—Cu)
por: Cruz-Enriquez, Adriana, et al.
Publicado: (2012)

Tetranuclear Cu(ii)-chiral complexes: synthesis, characterization and biological activity
por: Peewasan, Krisana, et al.
Publicado: (2019)

A “Naked” Fe(III)-(O(2)(2–))-Cu(II) Species Allows for Structural and Spectroscopic Tuning of Low-Spin Heme-Peroxo-Cu Complexes
por: Garcia-Bosch, Isaac, et al.
Publicado: (2015)

A novel tetranuclear Cu(ii) complex for DNA-binding and in vitro anticancer activity
por: Cao, Shuhua, et al.
Publicado: (2023)

catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]
por: Zeller, Matthias, et al.
Publicado: (2008)

catena-Poly[bis(μ(3)-2-phenylacetato-κ(3) O,O′:O)bis(μ(2)-2-phenylacetato-κ(2) O:O′)dicopper(II)(Cu—Cu)]
por: Benslimane, Meriem, et al.
Publicado: (2013)

Tuning of the Copper–Thioether Bond in Tetradentate N(3)S((thioether)) Ligands; O–O Bond Reductive Cleavage via a [Cu(II)(2)(μ-1,2-peroxo)](2+)/[Cu(III)(2)(μ-oxo)(2)](2+) Equilibrium
por: Kim, Sunghee, et al.
Publicado: (2014)

Cyclometalated Ir(III) Complex as a Metalloligand and a Selective Cu(II) Sensor: Synthesis and Structural Characterization of a Heterometallic Tetranuclear Ir(III)/Cu(II) Complex
por: Chandrasekhar, Vadapalli, et al.
Publicado: (2018)

Controlled Synthesis of Cu and Cu(2)O NPs and Incorporation of Octahedral Cu(2)O NPs in Cellulose II Films
por: Eivazihollagh, Alireza, et al.
Publicado: (2018)

Manipulating electron transfer – the influence of substituents on novel copper guanidine quinolinyl complexes
por: Heck, Joshua, et al.
Publicado: (2022)

Investigation of Luminescent Triplet States in Tetranuclear Cu(I) Complexes: Thermochromism and Structural Characterization
por: Boden, Pit, et al.
Publicado: (2021)

Crystal structure of catena-poly[hemi[1,3-bis(2,6-diisopropylphenyl)imidazolium] [[μ(3)-acetato-κ(3) O:O:O′-tri-μ(2)-acetato-κ(6) O:O′-dicopper(II)(Cu—Cu)]-μ-chlorido] dichloromethane sesquisolvate]
por: Iqbal, Mohammad, et al.
Publicado: (2015)

Tetrakis(μ-4-chlorobenzoato-κ(2) O:O′)bis[(ethanol-κO)copper(II)](Cu—Cu)
por: Mollica Nardo, Viviana, et al.
Publicado: (2013)

catena-Poly[[tetrakis(μ(2)-acetato-κ(2) O:O′)dicopper(II)(Cu—Cu)]-μ(2)-acetato-κ(2) O:O′-[bis[μ(2)-3-(dimethylamino)propan-1-olato]-κ(2) N,O:O;κ(2) O:N,O-bis[(tetrahydrofuran-κO)copper(II)]]-μ(2)-acetato-κ(2) O:O′]
por: Shahid, Muhammad, et al.
Publicado: (2008)

Tetra-μ-acetato-κ(8) O:O′-bis[(N-ethylpyrimidin-2-amine)copper(II)](Cu—Cu)
por: Aiyub, Zaharah, et al.
Publicado: (2010)

Diaquatetrakis(μ-3-methoxybenzoato-κ(2) O (1):O (1′))dicopper(II)
por: Srinivasan, Bikshandarkoil R., et al.
Publicado: (2020)

Encapsulation of tricopper cluster in a synthetic cryptand enables facile redox processes from Cu(I)Cu(I)Cu(I) to Cu(II)Cu(II)Cu(II) states
por: Zhang, Weiyao, et al.
Publicado: (2020)

Poly[[diaquabis(μ(3)-maleato-κ(4) O (1):O (1′),O (4):O(4′))dicopper(II)] trihydrate]
por: Farnum, Gregory A., et al.
Publicado: (2008)

Characterization of Cu(2)O/CuO heterostructure photocathode by tailoring CuO thickness for photoelectrochemical water splitting
por: Jeong, Dasol, et al.
Publicado: (2022)

Phase Equilibria and Crystal Chemistry in Portions of the System SrO-CaO-Bi(2)O(3)-CuO, Part II—The System SrO-Bi(2)O(3)-CuO
por: Roth, R. S., et al.
Publicado: (1990)

Ge–Cu-Complexes Ph(pyO)Ge(μ(2)-pyO)(2)CuCl and PhGe(μ(2)-pyO)(4)CuCl—Representatives of Cu(I)→Ge(IV) and Cu(II)→Ge(IV) Dative Bond Systems
por: Wagler, Jörg, et al.
Publicado: (2023)

Designing Highly Efficient Cu(2)O-CuO Heterojunction CO Oxidation Catalysts: The Roles of the Support Type and Cu(2)O-CuO Interface Effect
por: Zhao, Fen, et al.
Publicado: (2022)

Tetra-μ-acetato-κ(8) O:O′-bis[(2-phenoxypyrimidine-κN (1))copper(II)](Cu—Cu)
por: Fairuz, Zainal Abidin, et al.
Publicado: (2011)

Salinity-Based Toxicity of CuO Nanoparticles, CuO-Bulk and Cu Ion to Vibrio anguillarum
por: Rotini, Alice, et al.
Publicado: (2017)

Punicalagin Green Functionalized Cu/Cu(2)O/ZnO/CuO Nanocomposite for Potential Electrochemical Transducer and Catalyst
por: Fuku, X., et al.
Publicado: (2016)

Intermediate Cu(II)-Thiolate Species in the Reduction of Cu(II)GHK by Glutathione: A Handy Chelate for Biological Cu(II) Reduction
por: Ufnalska, Iwona, et al.
Publicado: (2021)

Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH(3)-Mediated Selective Catalytic Reduction
por: Negri, Chiara, et al.
Publicado: (2020)

Preparation of Biomass Carbon Composites MgO@ZnO@BC and Its Adsorption and Removal of Cu(II) and Pb(II) in Wastewater
por: Yang, Jie, et al.
Publicado: (2023)

Influence of Ag on the Structural, Electrochemical, Antibacterial, and Photocatalytic Performance of the (CuO–Cu(2)O)Cu Nanocomposite
por: Uma, B., et al.
Publicado: (2023)

Disproportionation of H(2)O(2) Mediated by Diiron-Peroxo Complexes as Catalase Mimics
por: Lakk-Bogáth, Dóra, et al.
Publicado: (2021)

Merging Cu(I) and Cu(II) Photocatalysis: Development of a Versatile Oxohalogenation Protocol for the Sequential Cu(II)/Cu(I)-Catalyzed Oxoallylation of Vinylarenes
por: Mandal, Tirtha, et al.
Publicado: (2023)

Tetrakis{2-[2-(2,6-dichloroanilino)phenyl]ethanoato-κ(2) O:O′}bis[(dimethyl sulfoxide-κO)copper(II)](Cu—Cu): a binuclear Cu(II) complex with the non-steroidal anti-inflammatory drug diclofenac
por: Sayen, Stéphanie, et al.
Publicado: (2012)

Tetra-μ-acetato-κ(8) O:O′-bis[(2-amino-3,5-dichloropyridine-κN (1))copper(II)](Cu—Cu)
por: Chang, Hui-Chang, et al.
Publicado: (2011)

Tetrakis[(3-hydroxypropyl)dimethylammonium] tetra-μ-acetato-κ(8) O:O′-bis[chloridocuprate(II)](Cu—Cu) dichloride
por: Shahid, Muhammad, et al.
Publicado: (2009)

Light-Irradiated Electrochemical Direct Construction of Cu(2)O/CuO Bilayers by Switching Cathodic/Anodic Polarization in Copper(II)–Tartrate Complex Aqueous Solution
por: Izaki, Masanobu, et al.
Publicado: (2019)

Synthesis of Cu(2)O/CuO Nanocrystals and Their Application to H(2)S Sensing
por: Mikami, Kazuki, et al.
Publicado: (2019)

Ethoxy Groups on ZrO(2), CuO, and CuO/ZrO(2) Studied by IR Spectroscopy
por: Podobiński, Jerzy, et al.
Publicado: (2022)

Hexanuclear Cu(3)O–3Cu triazole-based units as novel core motifs for high nuclearity copper(ii) frameworks
por: Ferrer, Sacramento, et al.
Publicado: (2019)

Study of the Glycerol Hydrogenolysis Reaction on Cu, Cu–Zn, and Cu–ZnO Clusters
por: Singh, Ram, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_r5gqlgdgo1nm8vfafjd2g1oaqa