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Studies on the Lithiation, Borylation, and 1,2‐Metalate Rearrangement of O‐Cycloalkyl 2,4,6‐Triisopropylbenzoates

A broad range of acyclic primary and secondary 2,4,6‐triisopropylbenzoate (TIB) esters have been used in lithiation‐borylation reactions, but cyclic TIB esters have not. We have studied the use of cyclic TIB esters in lithiation‐borylation reactions and looked at the effect of ring size (3‐ → 6‐memb...

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Detalles Bibliográficos
Autores principales: Mykura, Rory C., Songara, Pradip, Luc, Eugenia, Rogers, Jack, Stammers, Ellie, Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251992/
https://www.ncbi.nlm.nih.gov/pubmed/33651488
http://dx.doi.org/10.1002/anie.202101374