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Probing Physical Oxidation State by Resonant X‐ray Emission Spectroscopy: Applications to Iron Model Complexes and Nitrogenase

The ability of resonant X‐ray emission spectroscopy (XES) to recover physical oxidation state information, which may often be ambiguous in conventional X‐ray spectroscopy, is demonstrated. By combining Kβ XES with resonant excitation in the XAS pre‐edge region, resonant Kβ XES (or 1s3p RXES) data ar...

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Detalles Bibliográficos
Autores principales: Castillo, Rebeca G., Hahn, Anselm W., Van Kuiken, Benjamin E., Henthorn, Justin T., McGale, Jeremy, DeBeer, Serena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252016/
https://www.ncbi.nlm.nih.gov/pubmed/33497500
http://dx.doi.org/10.1002/anie.202015669