Cargando…
Probing Physical Oxidation State by Resonant X‐ray Emission Spectroscopy: Applications to Iron Model Complexes and Nitrogenase
The ability of resonant X‐ray emission spectroscopy (XES) to recover physical oxidation state information, which may often be ambiguous in conventional X‐ray spectroscopy, is demonstrated. By combining Kβ XES with resonant excitation in the XAS pre‐edge region, resonant Kβ XES (or 1s3p RXES) data ar...
Autores principales: | Castillo, Rebeca G., Hahn, Anselm W., Van Kuiken, Benjamin E., Henthorn, Justin T., McGale, Jeremy, DeBeer, Serena |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252016/ https://www.ncbi.nlm.nih.gov/pubmed/33497500 http://dx.doi.org/10.1002/anie.202015669 |
Ejemplares similares
-
Kβ X‐Ray Emission Spectroscopic Study of a Second‐Row Transition Metal (Mo) and Its Application to Nitrogenase‐Related Model Complexes
por: Castillo, Rebeca G., et al.
Publicado: (2020) -
Selenium Valence-to-Core
X-ray Emission Spectroscopy and Kβ HERFD X-ray
Absorption Spectroscopy as Complementary Probes of Chemical and Electronic
Structure
por: Henthorn, Justin T., et al.
Publicado: (2022) -
The Spectroscopy of Nitrogenases
por: Van Stappen, Casey, et al.
Publicado: (2020) -
Localized
Electronic Structure of Nitrogenase FeMoco
Revealed by Selenium K-Edge High Resolution X-ray Absorption
Spectroscopy
por: Henthorn, Justin T., et al.
Publicado: (2019) -
X‐ray Magnetic Circular Dichroism Spectroscopy Applied to Nitrogenase and Related Models: Experimental Evidence for a Spin‐Coupled Molybdenum(III) Center
por: Kowalska, Joanna K., et al.
Publicado: (2019)