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Orientational Jahn–Teller Isomerism in the Dark‐Stable State of Nature's Water Oxidase

The tetramanganese–calcium cluster of the oxygen‐evolving complex of photosystem II adopts electronically and magnetically distinct but interconvertible valence isomeric forms in its first light‐driven oxidized catalytic state, S(2). This bistability is implicated in gating the final catalytic state...

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Detalles Bibliográficos
Autores principales: Drosou, Maria, Zahariou, Georgia, Pantazis, Dimitrios A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252073/
https://www.ncbi.nlm.nih.gov/pubmed/33830630
http://dx.doi.org/10.1002/anie.202103425