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Orientational Jahn–Teller Isomerism in the Dark‐Stable State of Nature's Water Oxidase
The tetramanganese–calcium cluster of the oxygen‐evolving complex of photosystem II adopts electronically and magnetically distinct but interconvertible valence isomeric forms in its first light‐driven oxidized catalytic state, S(2). This bistability is implicated in gating the final catalytic state...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252073/ https://www.ncbi.nlm.nih.gov/pubmed/33830630 http://dx.doi.org/10.1002/anie.202103425 |