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Triarylmethanes and their Medium‐Ring Analogues by Unactivated Truce–Smiles Rearrangement of Benzanilides

Intramolecular nucleophilic aromatic substitution (Truce–Smiles rearrangement) of the anions of 2‐benzyl benzanilides leads to triarylmethanes in an operationally simple manner. The reaction succeeds even without electronic activation of the ring that plays the role of electrophile in the S(N)Ar rea...

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Detalles Bibliográficos
Autores principales: Abrams, Roman, Jesani, Mehul H., Browning, Alex, Clayden, Jonathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252078/
https://www.ncbi.nlm.nih.gov/pubmed/33830592
http://dx.doi.org/10.1002/anie.202102192