Evidence of the Lewis‐Amphoteric Character of Tris(pentafluoroethyl)silanide, [Si(C(2)F(5))(3)](−)

According to a first view on the geometrical and electronic structure of the tris(pentafluoroethyl)silanide, this anion appears as a Lewis base. Quantum chemical calculations on perfluoroalkylated silanides show significantly lower HOMO and LUMO energy levels in comparison to their non‐fluorinated c...

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Detalles Bibliográficos
Autores principales: Tiessen, Natalia, Keßler, Mira, Neumann, Beate, Stammler, Hans‐Georg, Hoge, Berthold
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252080/
https://www.ncbi.nlm.nih.gov/pubmed/33617080
http://dx.doi.org/10.1002/anie.202016455

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252080/
https://www.ncbi.nlm.nih.gov/pubmed/33617080
http://dx.doi.org/10.1002/anie.202016455

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