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Evidence of the Lewis‐Amphoteric Character of Tris(pentafluoroethyl)silanide, [Si(C(2)F(5))(3)](−)
According to a first view on the geometrical and electronic structure of the tris(pentafluoroethyl)silanide, this anion appears as a Lewis base. Quantum chemical calculations on perfluoroalkylated silanides show significantly lower HOMO and LUMO energy levels in comparison to their non‐fluorinated c...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252080/ https://www.ncbi.nlm.nih.gov/pubmed/33617080 http://dx.doi.org/10.1002/anie.202016455 |