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High‐pressure Nucleation of Low‐Density Polymorphs
New polymorphs β and γ of bis‐3‐nitrophenyl disulphide, crystallized above 0.3 GPa, are less dense than the ambient‐pressure polymorph α. This counterintuitive density relation results from the high‐entropy nucleation and subsequent kinetic crystallization. The work performed by pressure compensates...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252116/ https://www.ncbi.nlm.nih.gov/pubmed/33506549 http://dx.doi.org/10.1002/chem.202005121 |