Construction of Inorganic Crown Ethers by s‐Block‐Metal‐Templated Si−O Bond Activation

We herein report the synthesis, structures, coordination ability, and mechanism of formation of silicon analogs of crown ethers. An oligomerization of (2)D(2) (I) ((2)D(n),=(Me(4)Si(2)O)(n)) was achieved by the reaction with GaI(3) and MI(x) (M=Li, Na, Mg, Ca, Sr). In these reactions the metal catio...

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Detalles Bibliográficos
Autores principales: Dankert, Fabian, Richter, Roman‐Malte, Weigend, Florian, Xie, Xiulan, Balmer, Markus, von Hänisch, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252370/
https://www.ncbi.nlm.nih.gov/pubmed/33591587
http://dx.doi.org/10.1002/anie.202014822

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252370/
https://www.ncbi.nlm.nih.gov/pubmed/33591587
http://dx.doi.org/10.1002/anie.202014822

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