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Construction of Inorganic Crown Ethers by s‐Block‐Metal‐Templated Si−O Bond Activation
We herein report the synthesis, structures, coordination ability, and mechanism of formation of silicon analogs of crown ethers. An oligomerization of (2)D(2) (I) ((2)D(n),=(Me(4)Si(2)O)(n)) was achieved by the reaction with GaI(3) and MI(x) (M=Li, Na, Mg, Ca, Sr). In these reactions the metal catio...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252370/ https://www.ncbi.nlm.nih.gov/pubmed/33591587 http://dx.doi.org/10.1002/anie.202014822 |