Expanded Ring NHC Silver Carboxylate Complexes as Efficient and Reusable Catalysts for the Carboxylative Cyclization of Unsubstituted Propargylic Derivatives

Stabilized by a bulky N‐heterocyclic carbene [(BP)DPr, 1,3‐bis(2,6‐diisopropylphenyl)‐1,3‐diazonine‐2‐ylidene] ligand, new silver carboxylate complexes of the form (BP)DPrAgO(2)C‐R (R=Me, Ph) have been synthesized and fully characterized in solution and in the solid state and implemented as sole cat...

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Detalles Bibliográficos
Autores principales: Cervantes‐Reyes, Alejandro, Saxl, Tobias, Stein, Philipp M., Rudolph, Matthias, Rominger, Frank, Asiri, Abdullah M., Hashmi, A. Stephen K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252382/
https://www.ncbi.nlm.nih.gov/pubmed/33687152
http://dx.doi.org/10.1002/cssc.202002822

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252382/
https://www.ncbi.nlm.nih.gov/pubmed/33687152
http://dx.doi.org/10.1002/cssc.202002822

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