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Synthesis of Tetrahedranes Containing the Unique Bridging Hetero‐Dipnictogen Ligand EE′ (E ≠ E′=P, As, Sb, Bi)

In order to improve and extend the rare class of tetrahedral mixed main group transition metal compounds, a new synthetic route for the complexes [{CpMo(CO)(2)}(2)(μ,η(2):η(2)‐PE)] (E=As (1), Sb (2)) is described leading to higher yields and a decrease in reaction steps. Via this route, also the so...

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Detalles Bibliográficos
Autores principales: Dütsch, Luis, Riesinger, Christoph, Balázs, Gábor, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252408/
https://www.ncbi.nlm.nih.gov/pubmed/33844876
http://dx.doi.org/10.1002/chem.202100663