Ligand‐Constraint‐Induced Peroxide Activation for Electrophilic Reactivity

μ‐1,2‐peroxo‐bridged diiron(III) intermediates P are proposed as reactive intermediates in various biological oxidation reactions. In sMMO, P acts as an electrophile, and performs hydrogen atom and oxygen atom transfers to electron‐rich substrates. In cyanobacterial ADO, however, P is postulated to...

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Detalles Bibliográficos
Autores principales: Chandra, Anirban, Ansari, Mursaleem, Monte‐Pérez, Inés, Kundu, Subrata, Rajaraman, Gopalan, Ray, Kallol
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252416/
https://www.ncbi.nlm.nih.gov/pubmed/33843113
http://dx.doi.org/10.1002/anie.202100438

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252416/
https://www.ncbi.nlm.nih.gov/pubmed/33843113
http://dx.doi.org/10.1002/anie.202100438

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