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η(3)‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)

We present the η(3)‐coordination of the 2‐phosphaethynthiolate anion in the complex (PN)(2)La(SCP) (2) [PN=N‐(2‐(diisopropylphosphanyl)‐4‐methylphenyl)‐2,4,6‐trimethylanilide)]. Structural comparison with dinuclear thiocyanate‐bridged (PN)(2)La(μ‐1,3‐SCN)(2)La(PN)(2) (3) and azide‐bridged (PN)(2)La(...

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Detalles Bibliográficos
Autores principales: Watt, Fabian A., Burkhardt, Lukas, Schoch, Roland, Mitzinger, Stefan, Bauer, Matthias, Weigend, Florian, Goicoechea, Jose M., Tambornino, Frank, Hohloch, Stephan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252525/
https://www.ncbi.nlm.nih.gov/pubmed/33565689
http://dx.doi.org/10.1002/anie.202100559