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Infrared and NMR Spectroscopic Fingerprints of the Asymmetric H(7) (+)O(3) Complex in Solution

Infrared (IR) absorption in the 1000–3700 cm(−1) range and (1)H NMR spectroscopy reveal the existence of an asymmetric protonated water trimer, H(7) (+)O(3,) in acetonitrile. The core H(7) (+)O(3) motif persists in larger protonated water clusters in acetonitrile up to at least 8 water molecules. Qu...

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Detalles Bibliográficos
Autores principales: Kozari, Eve, Sigalov, Mark, Pines, Dina, Fingerhut, Benjamin P., Pines, Ehud
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252526/
https://www.ncbi.nlm.nih.gov/pubmed/33599024
http://dx.doi.org/10.1002/cphc.202001046