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Selective and Additive‐Free Hydrogenation of Nitroarenes Mediated by a DMSO‐Tagged Molecular Cobalt Corrole Catalyst

We report on the first cobalt corrole that effectively mediates the homogeneous hydrogenation of structurally diverse nitroarenes to afford the corresponding amines. The given catalyst is easily assembled prior to use from 4‐tert‐butylbenzaldehyde and pyrrole followed by metalation of the resulting...

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Detalles Bibliográficos
Autores principales: Timelthaler, Daniel, Schöfberger, Wolfgang, Topf, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252576/
https://www.ncbi.nlm.nih.gov/pubmed/34248412
http://dx.doi.org/10.1002/ejoc.202100073