Adducts of the Parent Boraphosphaketene H(2)BPCO and their Decarbonylative Insertion Chemistry

The first examples of Lewis base adducts of the parent boraphosphaketene (H(2)B‐PCO) and their cyclodimers are prepared. One of these adducts is shown to undergo mild decarbonylation and phosphinidene insertion into a B−C bond of a borole, forming very rare examples of 1,2‐phosphaborinines, B/P isos...

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Detalles Bibliográficos
Autores principales: Hagspiel, Stephan, Fantuzzi, Felipe, Dewhurst, Rian D., Gärtner, Annalena, Lindl, Felix, Lamprecht, Anna, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252595/
https://www.ncbi.nlm.nih.gov/pubmed/33843132
http://dx.doi.org/10.1002/anie.202103521

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252595/
https://www.ncbi.nlm.nih.gov/pubmed/33843132
http://dx.doi.org/10.1002/anie.202103521

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