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Adducts of the Parent Boraphosphaketene H(2)BPCO and their Decarbonylative Insertion Chemistry
The first examples of Lewis base adducts of the parent boraphosphaketene (H(2)B‐PCO) and their cyclodimers are prepared. One of these adducts is shown to undergo mild decarbonylation and phosphinidene insertion into a B−C bond of a borole, forming very rare examples of 1,2‐phosphaborinines, B/P isos...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252595/ https://www.ncbi.nlm.nih.gov/pubmed/33843132 http://dx.doi.org/10.1002/anie.202103521 |