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Three‐Component Self‐Assembly Changes its Course: A Leap from Simple Polymers to 3D Networks of Spherical Host–Guest Assemblies

One‐pot self‐assembly reactions of the polyphosphorus complex [Cp*Fe(η(5)‐P(5))] (A), a coinage metal salt AgSbF(6), and flexible aliphatic dinitriles NC(CH(2))(x)CN (x=1–10) yield 1D, 2D, and 3D coordination polymers. The seven‐membered backbone of the dinitrile was experimentally found as the bord...

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Detalles Bibliográficos
Autores principales: Peresypkina, Eugenia, Grill, Kevin, Hiltl, Barbara, Virovets, Alexander V., Kremer, Werner, Hilgert, Jan, Tremel, Wolfgang, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252601/
https://www.ncbi.nlm.nih.gov/pubmed/33686782
http://dx.doi.org/10.1002/anie.202103178