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Reduced Arene Complexes of Hafnium Supported by a Triamidoamine Ligand

A series of hafnium complexes with a reduced arene of the general formula [K(L)][Hf(Xy‐N(3)N)(arene)] (Xy‐N(3)N={(3,5‐Me(2)C(6)H(3))NCH(2)CH(2)}(3)N(3−), L=THF, 18‐crown‐6; arene=C(10)H(8) (2−), C(14)H(10) (2−)) mimic the chemistry of hafnium in its formal oxidation state +II. All compounds were obt...

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Detalles Bibliográficos
Autores principales: Ghana, Priyabrata, Schrader, Sebastian, Rajeshkumar, Thayalan, Spaniol, Thomas P., Englert, Ulli, Maron, Laurent, Okuda, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252659/
https://www.ncbi.nlm.nih.gov/pubmed/33890350
http://dx.doi.org/10.1002/anie.202103755