Highly Selective Ortho‐Directed Dicarboxylation of Cyclopentadiene by Methylcarbonates and CO(2) or COS – First Insight into Co‐ordination Chemistry of New Ambident Ligands

This research presents the highly regioselective syntheses of 1,2‐dicarboxylated cyclopentadienide salts [Cat](2)[C(5)H(3)(CO(2))(2)H] by reaction of a variety of organic cation methylcarbonate salts [Cat]OCO(2)Me (Cat=NR(4) (+), PR(4) (+), Im(+)) with cyclopentadiene (CpH) or by simply reacting org...

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Detalles Bibliográficos
Autores principales: Vollgraff, Tobias, Sundermeyer, Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252773/
https://www.ncbi.nlm.nih.gov/pubmed/33851453
http://dx.doi.org/10.1002/chem.202100300

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252773/
https://www.ncbi.nlm.nih.gov/pubmed/33851453
http://dx.doi.org/10.1002/chem.202100300

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