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Highly Selective Ortho‐Directed Dicarboxylation of Cyclopentadiene by Methylcarbonates and CO(2) or COS – First Insight into Co‐ordination Chemistry of New Ambident Ligands
This research presents the highly regioselective syntheses of 1,2‐dicarboxylated cyclopentadienide salts [Cat](2)[C(5)H(3)(CO(2))(2)H] by reaction of a variety of organic cation methylcarbonate salts [Cat]OCO(2)Me (Cat=NR(4) (+), PR(4) (+), Im(+)) with cyclopentadiene (CpH) or by simply reacting org...
Autores principales: | Vollgraff, Tobias, Sundermeyer, Jörg |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252773/ https://www.ncbi.nlm.nih.gov/pubmed/33851453 http://dx.doi.org/10.1002/chem.202100300 |
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