Changing the Reactivity of Zero‐ and Mono‐Valent Germanium with a Redox Non‐Innocent Bis(silylenyl)carborane Ligand

Using the chelating C,C′‐bis(silylenyl)‐ortho‐dicarborane ligand, 1,2‐(RSi)(2)‐1,2‐C(2)B(10)H(10) [R=PhC(NtBu)(2)], leads to the monoatomic zero‐valent Ge complex (“germylone”) 3. The redox non‐innocent character of the carborane scaffold has a drastic influence on the reactivity of 3 towards reduct...

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Detalles Bibliográficos
Autores principales: Yao, Shenglai, Kostenko, Arseni, Xiong, Yun, Lorent, Christian, Ruzicka, Ales, Driess, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252802/
https://www.ncbi.nlm.nih.gov/pubmed/33909944
http://dx.doi.org/10.1002/anie.202103769

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252802/
https://www.ncbi.nlm.nih.gov/pubmed/33909944
http://dx.doi.org/10.1002/anie.202103769

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