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Changing the Reactivity of Zero‐ and Mono‐Valent Germanium with a Redox Non‐Innocent Bis(silylenyl)carborane Ligand
Using the chelating C,C′‐bis(silylenyl)‐ortho‐dicarborane ligand, 1,2‐(RSi)(2)‐1,2‐C(2)B(10)H(10) [R=PhC(NtBu)(2)], leads to the monoatomic zero‐valent Ge complex (“germylone”) 3. The redox non‐innocent character of the carborane scaffold has a drastic influence on the reactivity of 3 towards reduct...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8252802/ https://www.ncbi.nlm.nih.gov/pubmed/33909944 http://dx.doi.org/10.1002/anie.202103769 |